Flux crystal growth of uranium(v) containing oxyfluoride perovskites-Reference-Cited by-同舟云学术

Flux crystal growth of uranium(v) containing oxyfluoride perovskites

Published:2019 Issue:11 Volume:6 Page:3203-3214
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Juillerat Christian A.¹²³⁴⁵^ORCID,Kocevski Vancho⁶²³⁴⁵^ORCID,Morrison Gregory¹²³⁴⁵^ORCID,Karakalos Stavros G.⁷²³⁴^ORCID,Patil Deepak⁸⁹¹⁰⁴^ORCID,Misture Scott T.⁸⁹¹⁰⁴^ORCID,Besmann Theodore M.⁶²³⁴⁵^ORCID,zur Loye Hans-Conrad¹²³⁴⁶^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of South Carolina

3. Columbia

4. USA

5. Center for Hierarchical Wasteform Materials (CHWM)

6. Nuclear Engineering Program

7. Department of Chemical Engineering

8. Kazuo Inamori School of Engineering

9. Alfred University

10. Alfred

Abstract

Crystals of three new uranium(v) containing oxyfluorides were grown out of an alkali fluoride flux and adopt a perovskite-type structure and are examined by SXRD, PXRD, XANES, XPS, EDS, magnetic susceptibility measurements, DFT calculations, and UV-vis spectroscopy.

Funder

Basic Energy Sciences

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QI/C9QI00537D

Reference63 articles.

1. Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective

2. Flux crystal growth: a versatile technique to reveal the crystal chemistry of complex uranium oxides