Synthetic routes to carbon substituted cobalt bis(dicarbollide) alkyl halides and aromatic amines along with closely related irregular pathways-Reference-Cited by-同舟云学术

Synthetic routes to carbon substituted cobalt bis(dicarbollide) alkyl halides and aromatic amines along with closely related irregular pathways

Published:2024 Issue:13 Volume:53 Page:5816-5826
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Nekvinda Jan¹^ORCID,Bavol Dmytro¹^ORCID,Litecká Miroslava¹^ORCID,Tüzün Ece Zeynep¹^ORCID,Dušek Michal²^ORCID,Grüner Bohumír¹^ORCID

Affiliation:

1. Institute of Inorganic Chemistry of the Czech Academy of Sciences, Hlavní 1001, Husinec-Řež 25068, Czech Republic

2. Institute of Physics of the Czech Academy of Sciences, Na Slovance 1999/2, Prague 8, 182 21, Czech Republic

Abstract

Carbon substituted cobalt bis(dicarbollide) alkyl halides [(1-X-(CH2)n-1,2-C2B9H10)(1,2-C2B9H11)-3,3′-Co]Me4N (X = Br, I; n = 1–3) are prepared in high yields (>90%) from their corresponding alcohols without side skeletal substitutions.

Funder

Grantová Agentura České Republiky

Ministerstvo Školství, Mládeže a Tělovýchovy

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00072B

Reference58 articles.

1. R. N.Grimes , Carboranes , Academic Press , 2016

2. Cobalt bis(dicarbollide) anion and its derivatives

3. R. N.Grimes , in Metallacarboranes of the transition and lanthanide elements , ed. A. Press , Elsevier , London, UK , 2016 , pp. 711–903

4. Chemistry of Cobalt Bis(dicarbollides). A Review

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1. Correction: Synthetic routes to carbon substituted cobalt bis(dicarbollide) alkyl halides and aromatic amines along with closely related irregular pathways;Dalton Transactions;2024