A two-dimensional conductive Mo-based covalent organic framework as an efficient electrocatalyst for nitrogen fixation-Reference-Cited by-同舟云学术

A two-dimensional conductive Mo-based covalent organic framework as an efficient electrocatalyst for nitrogen fixation

Published:2020 Issue:44 Volume:8 Page:23599-23606
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Wang Cong¹²³⁴⁵,Zhao Ying-Nan⁶⁷³⁴⁵,Zhu Chang-Yan¹²³⁴⁵,Zhang Min¹²³⁴⁵^ORCID,Geng Yun¹²³⁴⁵^ORCID,Li Yang-Guang⁶⁷³⁴⁵^ORCID,Su Zhong-Min¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Functional Material Chemistry

2. Faculty of Chemistry & National & Local United Engineering Laboratory for Power Battery

3. Northeast Normal University

4. Changchun 130024

5. China

6. Key Laboratory of Polyoxometalate Science of Ministry of Education

7. Faculty of Chemistry

Abstract

A two-dimensional conductive Mo-COF exhibits excellent electrocatalytic activity for N₂ reduction to NH₃ with an extremely low overpotential (0.16 V), effectively suppressing the competing hydrogen evolution reaction.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/TA/D0TA08676B

Reference64 articles.

1. Nitrogen Cycle Electrocatalysis

2. Catalysts for nitrogen reduction to ammonia

3. An Earth-system perspective of the global nitrogen cycle

4. The Haber-Bosch Process Revisited: On the Real Structure and Stability of “Ammonia Iron” under Working Conditions

5. Challenges in reduction of dinitrogen by proton and electron transfer

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