Augmentation of inductive effects through short range intramolecular hydrogen bonds for the improvement of cooperativity of trimeric rosettes-Reference-Cited by-同舟云学术

Augmentation of inductive effects through short range intramolecular hydrogen bonds for the improvement of cooperativity of trimeric rosettes

Published:2024 Issue:4 Volume:9 Page:345-351
ISSN:2058-9689
Container-title:Molecular Systems Design & Engineering
language:en
Short-container-title:Mol. Syst. Des. Eng.

Author:

Petelski Andre Nicolai¹^ORCID,Bundrea Tamara¹,Peruchena Nélida María²

Affiliation:

1. Departamento de Ingeniería Química, Universidad Tecnológica Nacional (UTN), Facultad Regional Resistencia (FRRe), CONICET, Centro de Investigación en Química e Ingeniería Teórica y Experimental (QUITEX), French 802, H3500CHJ, Resistencia, Chaco, Argentina

2. Laboratorio de Estructura Molecular y Propiedades (LEMyP), Instituto de Química Básica y Aplicada del Nordeste Argentino (IQUIBA-NEA), Consejo Nacional de Investigaciones Científicas y Técnicas, Universidad Nacional del Nordeste (UNNE-CONICET), Avenida Libertad 5460, 3400 Corrientes, Argentina

Abstract

Three key design elements improve the binding strength of trimeric rosettes: the direction of hydrogen bonds, the addition of groups with inductive effects, and the presence of ambifunctional intramolecular hydrogen bonds between the substituents.

Funder

Consejo Nacional de Investigaciones Científicas y Técnicas

Universidad Tecnológica Nacional

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/ME/D4ME00008K

Reference51 articles.

1. Wavy supramolecular polymers formed by hydrogen-bonded rosettes

2. A Coformer Approach for Supramolecular Polymerization at High Concentrations

3. Supramolecular Polymer Polymorphism: Spontaneous Helix–Helicoid Transition through Dislocation of Hydrogen-Bonded π-Rosettes

4. Tuning the Binding Strength of Even and Uneven Hydrogen-Bonded Arrays with Remote Substituents

5. How the Chalcogen Atom Size Dictates the Hydrogen‐Bond Donor Capability of Carboxamides, Thioamides, and Selenoamides

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