Two-dimensional infrared spectroscopy from the gas to liquid phase: density dependentJ-scrambling, vibrational relaxation, and the onset of liquid character
Author:
Affiliation:
1. Department of Chemistry
2. Boston University
3. Boston
4. USA
5. Photonics Center
6. University of Colorado
7. Boulder
8. Department of Physics
Abstract
Ultrafast 2DIR reveals rotational relaxation rates, critical slowing effects, and co-existence of free rotor and liquid populations in supercritical fluids.
Funder
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP04101J
Reference84 articles.
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2. A. I. Burshtein and S. I.Temkin , Spectroscopy of Molecular Rotation in Gases and Liquids , Cambridge University Press , Cambridge , 1994
3. P. Hamm and M. T.Zanni , Concepts and Methods of 2D Infrared Spectroscopy , Cambridge , 2011
4. ROTATIONAL RELAXATION RATE OF CO2 LASER LEVELS
5. J. Foster and R. S.Miller , in High Pressure Processes in Chemical Engineering , ed. M. Lackner , ProcessEng Engineering GmbH , 2010 , p. 53
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