Electronegativity principle for hydrogen evolution activity using first-principles calculations-Reference-Cited by-同舟云学术

Electronegativity principle for hydrogen evolution activity using first-principles calculations

Published:2023 Issue:19 Volume:25 Page:13289-13296
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

An Yi¹,Ouyang Min¹,Kong Shaoyu¹,Wang Guangjin²³,Chen Xiaobo¹^ORCID

Affiliation:

1. Siyuan Laboratory, Guangzhou Key Laboratory of Vacuum Coating Technologies and New Energy Materials, Guangdong Provincial Engineering Technology Research Center of Vacuum Coating Technologies and New Energy Materials, Department of Physics, Jinan University, Guangzhou, Guangdong 510632, China

2. School of Materials Science and Hydrogen Energy, Foshan University, Foshan 528000, China

3. Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, USA

Abstract

Catalysts with lower Mulliken electronegativity χ exhibit higher catalytic activity. This electronegativity principle is reaction route and pH independent and is founded on the thermoneutral requirement on ΔGH.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

Scientific and Technological Planning Project of Guangzhou City

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D2CP06067A

Reference44 articles.

1. Unraveling the rate-limiting step of two-electron transfer electrochemical reduction of carbon dioxide

2. Manipulating the oxygen reduction reaction pathway on Pt-coordinated motifs

3. Recent advancement in the electrocatalytic synthesis of ammonia

4. Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles

5. Electrocatalysis as an enabling technology for organic synthesis

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