Spectroscopic, structural and computational analysis of [Re(CO)3(dippM)Br]n+ (dippM = 1,1′-bis(diiso-propylphosphino)metallocene, M = Fe, n = 0 or 1; M = Co, n = 1)

Author:

Furneaux Aliza G.1234,Piro Nicholas A.1564,Hernández Sánchez Raúl7894,Gramigna Kathryn M.110114,Fey Natalie12131415ORCID,Robinson Michael J.1234,Kassel W. Scott1564,Nataro Chip1234

Affiliation:

1. Department of Chemistry

2. Lafayette College

3. Easton

4. USA

5. Villanova University

6. Villanova

7. Department of Chemistry and Chemical Biology

8. Harvard University

9. Cambridge

10. Brandeis University

11. Waltham

12. School of Chemistry

13. University of Bristol

14. Bristol BS8 1TS

15. UK

Abstract

[Re(CO)3(dippf)Br]+: the first structurally characterized complex of a coordinated bis(phosphino)ferrocenium ligand.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference51 articles.

1. K.-S. Gan and T. S. A.Hor, 1,1′-Bis(diphenylphosphino)ferrocene - Coordination Chemistry, Organic Synthesis and Catalysis, in Ferrocenes: Homogeneous Catalysis, Organic Synthesis, Materials Science, ed. A. Togni and T. Hayashi, VCH, Weinheim, Germany, 1995, pp. 3–104

2. S. W. Chien and T. S. A.Hor, The Coordination and Homogeneous Catalytic Chemistry of 1,1′-Bis(diphenylphosphino)ferrocene and its Chalcogenide Derivatives, in Ferrocenes: Ligands, Materials and Biomolecules, ed. P. Štěpnička, John Wiley & Sons Ltd., West Sussex, England, 2008, pp. 33–116

3. T. J. Colacot and S.Parisel, Synthesis, Coordination Chemistry and Catalytic Use of dppf Analogs, in Ferrocenes: Ligands, Materials and Biomolecules, ed. P. Štěpnička, John Wiley & Sons Ltd., West Sussex, England, 2008, pp. 117–140

4. Simple, Highly Active Palladium Catalysts for Ketone and Malonate Arylation:  Dissecting the Importance of Chelation and Steric Hindrance

5. An X-ray Study of the Effect of the Bite Angle of Chelating Ligands on the Geometry of Palladium(allyl) Complexes:  Implications for the Regioselectivity in the Allylic Alkylation

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