A broad view on the complexity involved in water oxidation catalysis based on Ru

A broad view on the complexity involved in water oxidation catalysis based on Ru–bpn complexes

Published:2020 Issue:47 Volume:49 Page:17375-17387
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ghaderian Abolfazl¹²³⁴⁵^ORCID,Franke Alicja⁶⁷⁸⁹,Gil-Sepulcre Marcos¹²³⁴^ORCID,Benet-Buchholz Jordi¹²³⁴^ORCID,Llobet Antoni¹²³⁴¹⁰^ORCID,Ivanović-Burmazović Ivana⁶⁷⁸⁹¹¹,Gimbert-Suriñach Carolina¹²³⁴^ORCID

Affiliation:

1. Institute of Chemical Research of Catalonia (ICIQ)

2. Barcelona Institute of Science and Technology

3. 43007 Tarragona

4. Spain

5. Departament de Química Física i Inorganica

6. Department of Chemistry and Pharmacy

7. Friedrich-Alexander University Erlangen-Nuremberg

8. 91058 Erlangen

9. Germany

10. Universitat Autònoma de Barcelona

11. Department Chemie

Abstract

The nature or the active species involved in the catalytic water oxidation by a new coordinatively saturated Ru complex with the formula [Ru(bpn)(pic)₂]Cl₂ (bpn: 2,2′-bi(1,10-phenanthroline), pic: 4-picoline) is investigated.

Funder

Ministerio de Economía y Competitividad

Agència de Gestió d’Ajuts Universitaris i de Recerca

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT03548C

Reference61 articles.

1. F. A. Cotton , G.Wilkinson , C. A.Murillo , M.Bochmann and R.Grimes , Advanced inorganic chemistry , Wiley New York , 1988

2. N. N. Greenwood and A.Earnshaw , Chemistry of the Elements , Elsevier , 2012

3. Ru-based oxidation catalysis

4. Non-innocent behaviour in mononuclear and polynuclear complexes: consequences for redox and electronic spectroscopic properties

5. S. Campagna , F.Puntoriero , F.Nastasi , G.Bergamini and V.Balzani , in Photochemistry and Photophysics of Coordination Compounds I , ed. V. Balzani and S. Campagna , Springer Berlin Heidelberg , Berlin, Heidelberg , 2007 , pp. 117–214

Cited by 9 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Capturing the Elusive [Ru^V═O]⁺ Intermediate in Water Oxidation;ACS Catalysis;2024-07-25

2. Aquabis(2,2′-bipyridine-κ² N,N′)(isonicotinamide-κN)ruthenium(II) bis(trifluoromethanesulfonate);IUCrData;2024-02-08

3. Solar fuel generation based on first-row transition metal catalysts;Photoelectrochemical Engineering for Solar Harvesting;2024

4. Metamorphic oxygen-evolving molecular Ru and Ir catalysts;Chemical Society Reviews;2023

5. Toward Escherichia coli bacteria-machine for water-oxidation reaction at neutral conditions: Using Ruthenium Red;International Journal of Hydrogen Energy;2023-01