Aggregated initiators: defining their role in the ROP of rac-lactide-Reference-Cited by-同舟云学术

Aggregated initiators: defining their role in the ROP of rac-lactide

Published:2018 Issue:31 Volume:47 Page:10626-10635
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Cols Jean-Marie E. P.¹²³⁴,Hill Victoria G.¹²³⁴,Williams Stella K.¹²³⁴,McIntosh Ruaraidh D.¹²³⁴^ORCID

Affiliation:

1. Institute of Chemical Sciences

2. Heriot-Watt University

3. Edinburgh

4. UK

Abstract

Reported examples of aggregated initiators for the ring-opening polymerisation (ROP) of lactide often lack detailed investigations as to the nature of the active species, making it difficult to reconcile ligand design with performance.

Funder

Heriot-Watt University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT01229F

Reference63 articles.

1. Single site catalysts for stereoselective ring-opening polymerization of lactides

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3. Flexible macrocycles as versatile supports for catalytically active metal clusters

4. Synthesis, Characterization, and Catalysis of Mixed-Ligand Lithium Aggregates, Excellent Initiators for the Ring-Opening Polymerization of l-Lactide

5. Ring-opening polymerization of cyclic esters initiated by lithium aggregate containing bis(phenolate) and enolate mixed ligands

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