Rhodium(<scp>i</scp>)-catalysed cycloisomerisation/6π electrocyclisation of 5-(ethynylamino)pent-2-yn-1-yl esters to 2,3-dihydrobenzo[<i>f</i>]indoles-Reference-Cited by-同舟云学术

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Rhodium(i)-catalysed cycloisomerisation/6π electrocyclisation of 5-(ethynylamino)pent-2-yn-1-yl esters to 2,3-dihydrobenzo[f]indoles

Published:2022 Issue:28 Volume:46 Page:13519-13523
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Merrett James Theodore¹,Chen Xiaoyu¹,Kyne Sara Helen¹^ORCID,Harode Mandeep¹,Chan Philip Wai Hong¹^ORCID

Affiliation:

1. School of Chemistry, Monash University, Clayton, Victoria, 3800, Australia

Abstract

A rare instance in rhodium catalysis of an in situ formed rhodacycle that undergoes a formal 1,8-acyloxy migration-initiated reductive elimination.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ01992B

Reference37 articles.

1. Transition metal-catalyzed reactions of propargylic carboxylates via an initial 1,2-acyloxy migration

2. Gold‐Catalyzed Cycloisomerizations of 1, n ‐Diyne Carbonates and Esters

3. Metal-catalyzed double migratory cascade reactions of propargylic esters and phosphates

4. Rhodium-catalyzed acyloxy migration of propargylic esters in cycloadditions, inspiration from the recent “gold rush”

5. Gold and platinum catalysis—a convenient tool for generating molecular complexity

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Rhodium-catalyzed annulation for the construction of indole core: An update;Tetrahedron;2023-10

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