Oxidation state variation in bis-calix[4]arene supported decametallic Mn clusters-Reference-Cited by-同舟云学术

Oxidation state variation in bis-calix[4]arene supported decametallic Mn clusters

Published:2021 Issue:47 Volume:50 Page:17566-17572
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wilson Lucinda R. B.¹^ORCID,Coletta Marco¹^ORCID,Jose Reshma²,Rajaraman Gopalan²^ORCID,Dalgarno Scott J.³^ORCID,Brechin Euan K.¹^ORCID

Affiliation:

1. EastCHEM School of Chemistry, The University of Edinburgh, David Brewster Road, Edinburgh, Scotland, EH9 3FJ, UK

2. Department of Chemistry, Indian Institute of Technology Bombay, Mumbai, 400076, India

3. Institute of Chemical Sciences, Heriot-Watt University, Riccarton, Edinburgh, Scotland, EH14 4AS, UK

Abstract

Isolation of structurally related [MnIII4MnII6] and [MnIII6MnII4] clusters using the 2,2′-bis-p-tBu-calix[4]arene ligand framework reveals significant differences in magnetic exchange interactions and spin frustration effects.

Funder

Science and Engineering Research Board

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT03410C

Reference28 articles.

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5. A Mixed-Valence Polyoxovanadate(III,IV) Cluster with a Calixarene Cap Exhibiting Ferromagnetic V(III)−V(IV) Interactions

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