The role of anionic processes in Li1−xNi0.44Mn1.56O4 studied by resonant inelastic X-ray scattering

Author:

Massel Felix1,Aktekin Burak2,Liu Yi-Sheng3ORCID,Guo Jinghua3ORCID,Sørby Magnus Helgerud4,Brandell Daniel2ORCID,Younesi Reza2ORCID,Hahlin Maria12ORCID,Duda Laurent-Claudius1ORCID

Affiliation:

1. Department of Physics and Astronomy, Division of X-ray Photon Science, Uppsala University, Box 516, S-751 20 Uppsala, Sweden

2. Department of Chemistry – Ångström Laboratory, Structural Chemistry, Uppsala University, Box 538, 751 21 Uppsala, Sweden

3. Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

4. Department for Hydrogen Technology, Institute for Energy Technology, P.O. Box 40, NO-2027 Kjeller, Norway

Abstract

We investigated the first lithiation cycle of the positive electrode material Li1−xNi0.44Mn1.56O4 (LNMO) using soft X-ray absorption spectroscopy (XAS) and resonant inelastic X-ray scattering (RIXS) at the transition metal L- and oxygen K-edges.

Funder

Energimyndigheten

Volkswagen Aktiengesellschaft

Scania

Vetenskapsrådet

Publisher

Royal Society of Chemistry (RSC)

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