A versatile iodo(iii)etherification of terminal ethynylsilanes using BF3–OiPr2 and alkyl benzyl ethers-Reference-Cited by-同舟云学术

A versatile iodo(iii)etherification of terminal ethynylsilanes using BF3–OiPr2 and alkyl benzyl ethers

Published:2021 Issue:17 Volume:19 Page:3825-3828
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Matsumoto Takuya¹²³⁴⁵^ORCID,Hagiyama Hiroshi¹⁶⁷⁸,Kuribayashi Kanetsugu¹²³⁴⁵,Hioki Kazuhito¹⁶⁷⁸,Fujita Hikaru¹²³⁴⁵^ORCID,Ochiai Masahito⁹¹⁰¹¹⁸,Kunishima Munetaka¹²³⁴⁵^ORCID

Affiliation:

1. Faculty of Pharmaceutical Sciences

2. Institute of Medical

3. Pharmaceutical

4. and Health Sciences

5. Kanazawa University

6. Kobe Gakuin University

7. Kobe 650-8586

8. Japan

9. Graduate School of Pharmaceutical Sciences

10. Tokushima University

11. Tokushima 770-8505

Abstract

BF₃–OⁱPr₂ and alkyl benzyl ether combining system enables a chemoselective alkoxyl group transfer in the synthesis of (E)-α-silyl-β-alkoxyvinyl-λ³-iodanes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB00479D

Reference23 articles.

1. The Chemistry of Enol Ethers

2. Cyclisation Reactions Involving Alkyl Enol Ethers

3. Nucleophilic vinylic substitutions of λ3-vinyliodanes

4. Transition Metal Organometallic Synthesis Utilising Diorganoiodine(III) Reagents

5. Advances in Synthetic Applications of Hypervalent Iodine Compounds

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2. Exploring New Reactions and Syntheses of Trivalent Iodine Compounds;Journal of Synthetic Organic Chemistry, Japan;2022-11-01