Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands: a case of dual emission revisited-Reference-Cited by-同舟云学术

Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands: a case of dual emission revisited

Published:2023 Issue:37 Volume:14 Page:10129-10139
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Johnson Catherine Ellen¹^ORCID,Schwarz Jesper²^ORCID,Deegbey Mawuli³^ORCID,Prakash Om²,Sharma Kumkum²,Huang Ping¹^ORCID,Ericsson Tore⁴,Häggström Lennart⁴,Bendix Jesper⁵,Gupta Arvind Kumar²^ORCID,Jakubikova Elena³^ORCID,Wärnmark Kenneth²^ORCID,Lomoth Reiner¹^ORCID

Affiliation:

1. Department of Chemistry –Ångström Laboratory, Uppsala University, Box 523, SE-75120 Uppsala, Sweden

2. Centre for Analysis and Synthesis, Department of Chemistry, Lund University, Box 124, SE-22100 Lund, Sweden

3. Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695, USA

4. Department of Physics – Ångström Laboratory, Uppsala University, Box 523, SE-751 20 Uppsala, Sweden

5. Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen, Denmark

Abstract

Photoluminescence of the FeIII complex occurs only from its 2LMCT state while its higher-energy but shorter-lived 2MLCT state is non-luminescent. Blue emission arises instead from a photoproduct of the non-emitting FeII complex.

Funder

National Science Foundation

Stiftelsen för Strategisk Forskning

Liam M. Kinne Foundation

Knut och Alice Wallenbergs Stiftelse

Sten K Johnsons stiftelse

Kungliga Fysiografiska Sällskapet i Lund

Vetenskapsrådet

Energimyndigheten

Publisher

Royal Society of Chemistry (RSC)

Subject