A porphyrin pentamer as a bright emitter for NIR OLEDs

Author:

Tejerina Lara1,Rapidis Alexandros G.2ORCID,Rickhaus Michel1,Murto Petri3ORCID,Genene Zewdneh3,Wang Ergang3ORCID,Minotto Alessandro2,Anderson Harry L.1ORCID,Cacialli Franco2ORCID

Affiliation:

1. Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Oxford OX1 3TA, UK

2. Department Physics and Astronomy and London Centre for Nanotechnology, University College London, London WC1E 6BT, UK

3. Department of Chemistry and Chemical Engineering/Applied Chemistry, Chalmers University of Technology, Gothenburg, SE-412 96, Sweden

Abstract

NIR OLEDs are achieved by blending ethyne-linked zinc(II) porphyrin pentamers into a red-emitting push–pull polymeric host matrix (PIDT-2TPD). We report external quantum efficiencies of 2.0 % with peak emission at 830 nm, confirming the promise of porphyrin oligomers for non-toxic NIR OLEDs.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Engineering and Physical Sciences Research Council

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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