Novel iodoargentates [Mn(4,4′-bpy)(DMF)3(H2O)] Ag5I7·4,4′-bpy (1), [Mn(4,4′-bpy)(DMSO)4]2Ag11I15(2), [Mn(4,4′-bpy)2(DMSO)2(H2O)2]Ag10I12·2DMSO·2H2O (3) and [Mn2(4,4′-bpy)2(DMF)5(DMSO)2(H2O)]Ag10I14·2DMF (4) were prepared, templated by solvated [Mn(4,4′-bpy)]2+cations.