Redox mediators for oxygen reduction reactions in lithium–oxygen batteries: governing kinetics and its implications

Author:

Ko Youngmin1ORCID,Kim Kyoungoh1,Yoo Jaekyun1,Kwon Giyun1,Park Hyeokjun12,Kim Jihyeon1,Lee Byungju13,Song Jun-Hyuk1,Kim Jinsoo4,Kang Kisuk12567ORCID

Affiliation:

1. Department of Materials Science and Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of Korea

2. Department of Materials Science and Engineering, Research Institute of Advanced Materials (RIAM), Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of Korea

3. Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA

4. Ulsan Advanced Energy Technology R&D Center, Korea Institue of Energy Research, Ulsan, Republic of Korea

5. School of Chemical and Biological Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of Korea

6. Institute of Engineering Research, College of Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of Korea

7. Center for Nanoparticle Research, Institute of Basic Science, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of Korea

Abstract

Intrinsic properties of quinones such as steric hindrance and heterogeneous electron transfer kinetics that follows Marcus theory concurrently govern their performance as redox mediators for oxygen reduction reactions in lithium–oxygen batteries.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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