Taking a closer look – how the microstructure of Dion–Jacobson perovskites governs their photophysics

Author:

Kahmann Simon12ORCID,Duim Herman3,Rommens Alexander J.3,Frohna Kyle12ORCID,ten Brink Gert H.4ORCID,Portale Giuseppe5ORCID,Stranks Samuel D.12ORCID,Loi Maria A.3ORCID

Affiliation:

1. Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, UK

2. Department of Chemical Engineering and Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, UK

3. Photophysics and OptoElectronics Group, Zernike Institute of Advanced Materials, University of Groningen, Nijenborgh 4 NL-9747 AG, Groningen, The Netherlands

4. Nanostructured Materials and Interfaces, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, NL-9747 AG Groningen, The Netherlands

5. Macromolecular Chemistry and New Polymeric Materials, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, NL-9747 AG Groningen, The Netherlands

Abstract

Films of the two-dimensional Dion–Jacobson compound PDMAPbI4 are studied through concerted multimodal microscopy. Hyperspectral Raman and PL imaging underline the complex impact of the microstructure, composition, and orientation on the photophysics.

Funder

Deutscher Akademischer Austauschdienst

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

H2020 European Research Council

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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