Cation exchange in an anionic metal–organic framework enhancing propylene/propane separation-Reference-Cited by-同舟云学术

Cation exchange in an anionic metal–organic framework enhancing propylene/propane separation

Published:2023 Issue:43 Volume:25 Page:6039-6043
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Zhang Xue¹,Tang Hui-Juan¹,Zeng Min¹^ORCID,Yang Rong¹,Wang Yu¹^ORCID,Chen Kai-Jie¹^ORCID

Affiliation:

1. Key Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology, Xi'an Key Laboratory of Functional Organic Porous Materials, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an, Shaanxi, 710072, China

Abstract

Exchanging dimethylamine cations with smaller K+ ions in an anionic MOF can significantly increase the pore volume and provide preferable interactions for C3H6, resulting in improved adsorption capacity and selectivity of C3H6/C3H8.

Funder

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CE/D3CE00761H

Reference43 articles.

1. Seven chemical separations to change the world

2. Prediction of boiling points and critical temperatures of industrially important organic compounds from molecular structure

3. A metal-organic framework–based splitter for separating propylene from propane

4. Synergistic sorbent separation for one-step ethylene purification from a four-component mixture

5. Selective Aerobic Oxidation of a Metal–Organic Framework Boosts Thermodynamic and Kinetic Propylene/Propane Selectivity

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