Affiliation:
1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Science 49 Tropinin str., Nizhny Novgorod 603137, Russia
Abstract
Interaction of 1,4-dichloro-3,6a-diaza-1,4-diphosphapentalenes with alkali metals leads to the cleavage of the N–N bond and the formation of isomeric heteropentalenes as intermediates, which further transform into aromatic 1,2,3-azadiphospholides.
Funder
Russian Foundation for Basic Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Cited by
6 articles.
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1. Reactivity of 1,4-dichloro-3a,6a-diaza-1,4-diphosphapentalenes towards phenoxides, alkoxides, and phenols;Russian Chemical Bulletin;2023-12
2. 2-Thienyl-substituted 3a,6a-diaza-1,4-diphosphapentalene: Synthesis and complexation with 1,2,4,5-tetracyanobenzene;Mendeleev Communications;2023-09
3. 2,3,5,6-Tetramethyl-1H,4H-3a,6a-diaza-1,4-diphosphapentalene and Its 1,4-Dichloro Derivative: Specifics of Synthetic Approaches;Russian Journal of General Chemistry;2023-08
4. A New Class of Two‐Deck Dicationic Heteropentalenes Existing by the Balance between Interdeck Aromaticity and Covalent P−P Bonding;European Journal of Inorganic Chemistry;2023-06-20
5. Hemetsberger–Knittel and Ketcham Synthesis of Heteropentalenes with Two (1:1), Three (1:2)/(2:1) and Four (2:2) Heteroatoms;Reactions;2023-05-08