A self-regulated gradient interphase for dendrite-free solid-state Li batteries

Author:

Wang Tengrui1,Duan Jian1,Zhang Bao2,Luo Wei1ORCID,Ji Xiao2,Xu Henghui34,Huang Ying1,Huang Liqiang1,Song Zhenyou1,Wen Jiayun1,Wang Chunsheng2ORCID,Huang Yunhui4ORCID,Goodenough John B.3ORCID

Affiliation:

1. Institute of New Energy for Vehicles, School of Materials Science and Engineering, Tongji University, Shanghai 201804, China

2. Department of Chemical & Biomolecular Engineering, University of Maryland College Park, College Park, Maryland, 20742, USA

3. Materials Science and Engineering Program and Department of Mechanical Engineering, The University of Texas at Austin, Austin 78712 TX, USA

4. State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

Abstract

A functional gradient lithium anode (FGLA), where a LiF-rich layer faces garnet side and gradually changes to a LiAl-rich layer facing Li side, effectively prevents solid-state electrolytes from dendrite penetration at high current densities.

Funder

Shanghai Rising-Star Program

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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