A C(π-hole)⋯Cl–Zn tetrel interaction driving a metal–organic supramolecular assembly-Reference-Cited by-同舟云学术

A C(π-hole)⋯Cl–Zn tetrel interaction driving a metal–organic supramolecular assembly

Published:2020 Issue:42 Volume:22 Page:6979-6982
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Ramírez de Arellano Carmen¹²³⁴^ORCID,Adam Rosa¹²³⁴,Ballesteros-Garrido Rafael¹²³⁴^ORCID,Abarca Belen¹²³⁴,Ballesteros Rafael¹²³⁴^ORCID,Alcorta Ibon⁵⁶⁷⁴^ORCID,Elguero José⁵⁶⁷⁴,Escrivà Emilio⁸²³⁴

Affiliation:

1. Departamento de Química Orgánica

2. Universidad de Valencia

3. 46100 Valencia

4. Spain

5. Instituto de Química Médica

6. Consejo Superior de Investigaciones Científicas (CSIC)

7. 28006 Madrid

8. Departamento de Química Inorgánica

Abstract

A brominated pyrimidinyl triazolopyridine ligand (bptpy) forms a C(π-hole)⋯Cl–Zn tetrel interaction that drives the formation of supramolecular layers through chain assembly in 18 membered metallacycle [(ZnCl₂)₂(μ-bptpy)₂] crystals.

Funder

Universitat de València

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CE/D0CE01272F

Reference37 articles.

1. The Hydrogen Bond. A Bond for Life

2. Crystal Engineering: An Outlook for the Future

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5. Halogen bonding for molecular recognition: new developments in materials and biological sciences

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1. Fused aza-heterocyclic ligands: expanding the MOF chemist's toolbox;CrystEngComm;2022

2. Can metal halides be electron donors in σ‐hole and π‐hole tetrel bonds? Cooperativity with an alkaline‐earth bond;International Journal of Quantum Chemistry;2021-07-14

3. Correction: A C(π-hole)⋯Cl–Zn tetrel interaction driving a metal–organic supramolecular assembly;CrystEngComm;2020