Theoretical investigation of tetrahedral distortion of four-coordinate iron(ii) centres in FePd(CN)4
Author:
Affiliation:
1. Nanostructures Research Laboratory
2. Japan Fine Ceramics Center
3. Nagoya 456-8587
4. Japan
5. Department of Chemistry
6. Faculty of Science
7. Kyushu University
8. Fukuoka 819-0395
Abstract
The Jahn–Teller-like effect on the tetrahedral geometry of d6 iron(ii) is caused by its unequally occupied e orbitals with non-bonding nature.
Funder
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04155F
Reference51 articles.
1. Jahn–Teller distortions in transition metal compounds, and their importance in functional molecular and inorganic materials
2. Modern Aspects of the Jahn−Teller Effect Theory and Applications To Molecular Problems
3. Evolution of the Jahn−Teller Distortion of MnO6 Octahedra in RMnO3 Perovskites (R = Pr, Nd, Dy, Tb, Ho, Er, Y): A Neutron Diffraction Study
4. Bond-length fluctuations and the spin-state transition inLCoO3(L=La,Pr, and Nd)
5. Structure of Jahn–Teller distorted solvated copper(ii) ions in solution, and in solids with apparently regular octahedral coordination geometry
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1. Computational and Experimental Determination of the Electronic Structure and Optical Properties of Three-Dimensional Zn[M(CN)4] Tetracyanates (M = Ni, Pd, and Pt);The Journal of Physical Chemistry C;2023-08-03
2. Studies on dynamic structures constructed by anisotropic assemblies of tetracyanometallate units;Bulletin of Japan Society of Coordination Chemistry;2023-05-31
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