Sustainable high-energy aqueous zinc–manganese dioxide batteries enabled by stress-governed metal electrodeposition and fast zinc diffusivity

Author:

Yang Huijun1,Zhu Ruijie2,Yang Yang3,Lu Ziyang3,Chang Zhi1,He Ping4ORCID,Zhu Chunyu5ORCID,Kitano Sho6ORCID,Aoki Yoshitaka6ORCID,Habazaki Hiroki6ORCID,Zhou Haoshen14ORCID

Affiliation:

1. Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology, Umezono, Tsukuba 305-8568, Japan

2. Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan

3. Graduate School of System and Information Engineering, University of Tsukuba, 1-1-1, Tennoudai, Tsukuba 305-857, Japan

4. Center of Energy Storage Materials Technology, College of Engineering and Applied Sciences, Jiangsu Key Laboratory of Artificial Functional Materials, National Laboratory of Solid State Microstructures, and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China

5. School of Electrical and Power Engineering, China University of Mining and Technology, Xuzhou 221116, China

6. Division of Applied Chemistry, Faculty of Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan

Abstract

Beyond the fragile glass fiber separator, we demonstrated a polymer separator with good mechanical strength and fast Zn2+ diffusivity, which synergistically mitigates Zn dendrite formation and improves Zn reversibility at high capacity.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Science and Technology Support Program of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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