Spin-state dependent pressure responsiveness of Fe(<scp>ii</scp>)-based triazolate metal–organic frameworks-Reference-Cited by-同舟云学术

Spin-state dependent pressure responsiveness of Fe(ii)-based triazolate metal–organic frameworks

Published:2024 Issue:14 Volume:12 Page:4954-4960
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Kronawitter Silva M.¹^ORCID,Röβ-Ohlenroth Richard²^ORCID,Hallweger Sebastian A.¹^ORCID,Hirrle Marcel²,Krug von Nidda Hans-Albrecht³,Luxenhofer Tobias²,Myatt Emily⁴^ORCID,Pitcairn Jem⁴^ORCID,Cliffe Matthew J.⁴^ORCID,Daisenberger Dominik⁵^ORCID,Wojciechowski Jakub⁶,Volkmer Dirk²^ORCID,Kieslich Gregor¹^ORCID

Affiliation:

1. Technical University of Munich, TUM Natural School of Sciences, Lichtenbergstr. 4, Garching 85748, Germany

2. Chair of Solid State and Materials Chemistry, Institute of Physics, University of Augsburg, Universitätsstr. 1, Augsburg 86159, Germany

3. Experimental Physics V, Center for Electronic Correlations and Magnetism, Institute of Physics, University of Augsburg, Universitätsstr. 1, Augsburg 86159, Germany

4. School of Chemistry, University of Nottingham, Nottingham NG7 2RD, UK

5. Diamond Light Source Ltd., Diamond House, Harwell Campus, Didcot OX11 ODE, UK

6. Rigaku Europe SE, Hugenottenallee 167, Neu-Isenburg, Germany

Abstract

We applied Fe(ii)-based MOFs with different spin-states to investigate the impact of Fe(ii) spin-state on the bulk modulus. The results emphasize the complex parameter space that determines the mechanical properties of MOFs.

Funder

Deutsche Forschungsgemeinschaft

UK Research and Innovation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TC/D4TC00360H

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