Halogenation affects driving forces, reorganization energies and “rocking” motions in strained [Fe(tpy)2]2+ complexes-Reference-Cited by-同舟云学术

Halogenation affects driving forces, reorganization energies and “rocking” motions in strained [Fe(tpy)2]2+ complexes

Published:2021 Issue:41 Volume:50 Page:14566-14575
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kwon Hyuk-Yong¹^ORCID,Ashley Daniel C.¹^ORCID,Jakubikova Elena¹^ORCID

Affiliation:

1. Department of Chemistry, North Carolina State University, 2620 Yarbrough Dr., Raleigh, NC 27695, USA

Abstract

Halogenation of [Fe(tpy)2]2+ at 6 and 6′′ positions of tpy has a clear and predictable impact on the tpy ligand “rocking” motion that is correlated to numerous other geometrical distortions and reorganization energies for spin-state changes.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02314D

Reference80 articles.

1. Ironing out the photochemical and spin-crossover behavior of Fe(II) coordination compounds with computational chemistry

2. Switching of Molecular Spin States in Inorganic Complexes by Temperature, Pressure, Magnetic Field and Light: Towards Molecular Devices

3. Multifunctionality in spin crossover materials

4. Electron-Induced Spin Crossover of Single Molecules in a Bilayer on Gold

5. Spintronics: Fundamentals and applications

Cited by 7 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. A Survey of the Angular Distortion Landscape in the Coordination Geometries of High-Spin Iron(II) 2,6-Bis(pyrazolyl)pyridine Complexes;Inorganic Chemistry;2024-01-23

2. Activating a high-spin iron(ii) complex to thermal spin-crossover with an inert non-isomorphous molecular dopant;Dalton Transactions;2024

3. Desolvation of metal complexes to construct metal–organic framework glasses;Nature Synthesis;2023-10-09

4. Spin State in Homoleptic Iron(II) Terpyridine Complexes Influences Mixed Valency and Electrocatalytic CO₂ Reduction;Inorganic Chemistry;2023-04-12

5. Molecular Engineering to Tune Functionality: The Case of Cl-Substituted [Fe(terpy)₂]²⁺;Inorganic Chemistry;2023-04-11