Halogenation affects driving forces, reorganization energies and “rocking” motions in strained [Fe(tpy)2]2+ complexes

Author:

Kwon Hyuk-Yong1ORCID,Ashley Daniel C.1ORCID,Jakubikova Elena1ORCID

Affiliation:

1. Department of Chemistry, North Carolina State University, 2620 Yarbrough Dr., Raleigh, NC 27695, USA

Abstract

Halogenation of [Fe(tpy)2]2+ at 6 and 6′′ positions of tpy has a clear and predictable impact on the tpy ligand “rocking” motion that is correlated to numerous other geometrical distortions and reorganization energies for spin-state changes.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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