The non-planarity of the benzene molecule in the X-ray structure of the chelated bismuth(iii) heteroboroxine complex is not supported by quantum mechanical calculations-Reference-Cited by-同舟云学术

The non-planarity of the benzene molecule in the X-ray structure of the chelated bismuth(iii) heteroboroxine complex is not supported by quantum mechanical calculations

Published:2016 Issue:2 Volume:45 Page:462-465
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fanfrlík Jindřich¹²³⁴,Sedlak Robert¹²³⁴,Pecina Adam¹²³⁴,Rulíšek Lubomír¹²³⁴,Dostál Libor⁵⁶⁷⁸⁴,Moncóľ Ján⁹¹⁰¹¹¹¹¹²,Růžička Aleš⁵⁶⁷⁸⁴,Hobza Pavel¹²³⁴¹³

Affiliation:

1. Institute of Organic Chemistry and Biochemistry

2. Academy of Sciences of the Czech Republic

3. 166 10 Prague 6

4. Czech Republic

5. Department of General and Inorganic Chemistry

6. Faculty of Chemical Technology

7. University of Pardubice

8. Pardubice

9. Institute of Inorganic Chemistry

10. Faculty of Chemical and Food Technology

11. Slovak University of Technology

12. SK-812 37 Bratislava

13. Regional Centre of Advanced Technologies and Materials

Abstract

The competition of two σ-hole(Bi)⋯π interactions is responsible for disorder of the benzene moiety in the crystal of bismuth(iii) heteroboroxine–benzene complex.

Funder

Czech Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04381F

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