Oxidation catalyst obtained by the immobilization of layered double hydroxide/Mn(iii) porphyrin on monodispersed silica spheres

Author:

Mantovani Karen Mary12345ORCID,Molgero Westrup Kátia Cristina12345ORCID,da Silva Junior Renaldo Marcos12345ORCID,Jaerger Silvia62345ORCID,Wypych Fernando62345ORCID,Nakagaki Shirley12345ORCID

Affiliation:

1. Laboratório de Bioinorgânica e Catálise

2. Departamento de Química

3. Universidade Federal do Paraná

4. Curitiba

5. Brazil

6. Laboratório de Química de Materiais Avançados

Abstract

Monodispersed hierarchical layered double hydroxide on silica spheres (LDH@SiO2) with core–shell structures were developed for metalloporphyrin immobilization and the materials were used as oxidant catalysts of different substrates.

Funder

Financiadora de Estudos e Projetos

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference33 articles.

1. L. R. Milgrom , The Colours of Life. An introduction to the Chemistry of Porphyrins and Related Compounds , Oxford University Press , Oxford , 1997

2. K. M. Smith , Porphyrins and metalloporphyrins: A New Edition Based on the Original Volume by J. E. Falk , Elsevier Sci. Pub. Co. , New York , 1975

3. K. M. Kadish , K. M.Smith and R.Guilard , The porphyrin handbook vol. 6, Applications: Past, Present and Future , Academic Press , San Diego , 2000

4. A brief history of the contribution of metalloporphyrin models to cytochrome P450 chemistry and oxidation catalysis

5. J. T. Groves , K.Shalyaev and J.Lee , Oxometalloporphyrins in Oxidative Catalysis , in The Porphyrin Handbook , ed. K. M. Kadish , K. M. Smith and R. Guilard , Academic Press , San Diego, CA and Burlington, MA , 1999 , ch. 27, vol. 4 , pp. 17–40

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