An IrIV-containing polyoxometalate

Author:

Adonin Sergey A.12342,Izarova Natalya V.5678,Besson Claire56789,Abramov Pavel A.12342,Santiago-Schübel Beatrix1011678,Kögerler Paul56789ORCID,Fedin Vladimir P.12342,Sokolov Maxim N.12342

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry SB RAS

2. 630090 Novosibirsk

3. Russia

4. Novosibirsk State University

5. Peter Grünberg Institute – PGI 6

6. Forschungszentrum Jülich

7. D-52425 Jülich

8. Germany

9. Institute of Inorganic Chemistry

10. Central Institute for Engineering

11. Electronics and Analytics – ZEA 3

Abstract

In situ formation of Ir(iv) oxo-hydroxo complexes, coupled with a gradual release of tungstate ions, results in the redox-active Anderson–Evans-type polyanion [IrIVW6O24]8−.

Funder

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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