Zinc(ii)-catalyzed reactions of carbon dioxide and propargylic alcohols to carbonates at room temperature-Reference-Cited by-同舟云学术

Zinc(ii)-catalyzed reactions of carbon dioxide and propargylic alcohols to carbonates at room temperature

Published:2016 Issue:2 Volume:18 Page:382-385
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Hu Jiayin¹²³⁴⁵,Ma Jun¹²³⁴⁵,Zhu Qinggong¹²³⁴⁵,Qian Qingli¹²³⁴⁵,Han Hongling¹²³⁴⁵,Mei Qingqing¹²³⁴⁵,Han Buxing¹²³⁴⁵

Affiliation:

1. Beijing National Laboratory for Molecular Sciences

2. CAS Key Laboratory of Colloid

3. Interface and Chemical Thermodynamics

4. Institute of Chemistry

5. Chinese Academy of Sciences

Abstract

ZnI₂/NEt₃ can catalyze the reactions of CO₂ and propargylic alcohols to form α-alkylidene cyclic carbonates effectively at room temperature under solvent-free conditions, and the yields of the desired products can reach 99%.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/GC/C5GC01870F

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