HydG, the “dangler” iron, and catalytic production of free CO and CN−: implications for [FeFe]-hydrogenase maturation-Reference-Cited by-同舟云学术

HydG, the “dangler” iron, and catalytic production of free CO and CN−: implications for [FeFe]-hydrogenase maturation

Published:2021 Issue:30 Volume:50 Page:10405-10422
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Shepard Eric M.¹²³⁴,Impano Stella¹²³⁴,Duffus Benjamin R.¹²³⁴^ORCID,Pagnier Adrien¹²³⁴^ORCID,Duschene Kaitlin S.¹²³⁴,Betz Jeremiah N.¹²³⁴,Byer Amanda S.¹²³⁴^ORCID,Galambas Amanda¹²³⁴,McDaniel Elizabeth C.¹²³⁴,Watts Hope¹²³⁴,McGlynn Shawn E.⁵⁶⁷⁸^ORCID,Peters John W.⁹¹⁰¹¹⁴^ORCID,Broderick William E.¹²³⁴^ORCID,Broderick Joan B.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry & Biochemistry

2. Montana State University

3. Bozeman

4. USA

5. Earth-Life Science Institute

6. Tokyo Institute of Technology

7. Meguro-ku

8. Japan

9. Institute of Biological Chemistry

10. Washington State University

11. Pullman

Abstract

The hydrogenase maturase HydG produces multiple equivalents of free CO and CN⁻ during catalysis. This production correlates with the activation of hydrogenase, supporting a model in which free CO and CN⁻ are relevant to maturation.

Funder

Basic Energy Sciences

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01359A

Reference110 articles.

1. Hydrogenases

2. [FeFe]- and [NiFe]-hydrogenase diversity, mechanism, and maturation