Mono- and dinuclear zirconocene(<scp>iv</scp>) amide complexes for the catalytic dehydropolymerisation of phenylsilane-Reference-Cited by-同舟云学术

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Mono- and dinuclear zirconocene(iv) amide complexes for the catalytic dehydropolymerisation of phenylsilane

Published:2022 Issue:40 Volume:12 Page:26277-26283
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Lindenau Kevin¹,Spannenberg Anke¹,Reiß Fabian¹^ORCID,Beweries Torsten¹^ORCID

Affiliation:

1. Leibniz-Institut für Katalyse e.V., Albert-Einstein-Str. 29a, 18059 Rostock, Germany

Abstract

Mono- and dinuclear zirconocene amide complexes were tested as catalysts for the dehydropolymerisation of phenylsilane. The dinuclear complex is surprisingly stable, producing mixtures of polysilanes and cyclic oligomers.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D2RA04955D

Reference65 articles.

1. J.Koe , M.Fujiki , Organosilicon Compounds , ed. V. Y. Lee , Academic Press , 2017 , pp. 219–300

2. J. R.Koe , Comprehensive Organometallic Chemistry III , ed. D. M. P. Mingos and R. H. Crabtree , Elsevier , Oxford , 2007 , pp. 549–649

3. Applications of Inorganic Polymeric Materials II: Polysilanes

4. Polysilane high polymers

5. Contemporary polysilane synthesis and functionalisation

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