Insertion of terminal alkyne into Pt–N bond of the square planar [PtI2(Me2phen)] complex

Author:

Benedetti Michele1234ORCID,De Castro Federica1234ORCID,Lamacchia Vincenza5674,Pacifico Concetta5674,Natile Giovanni5674,Fanizzi Francesco P.1234ORCID

Affiliation:

1. Dipartimento di Scienze e Tecnologie Biologiche ed Ambientali

2. Università del Salento

3. I-73100 Lecce

4. Italy

5. Dipartimento di Chimica

6. Università degli Studi di Bari

7. I-70125 Bari

Abstract

The reactivity of [PtX2(Me2phen)] complexes (X = Cl, Br, I; Me2phen = 2,9-dimethyl-1,10-phenanthroline) with terminal alkynes is reported. Bromo and iodo derivatives lead to the formation of Pt(ii) alkenyl derivatives of the type [PtX22-N,C-(Z)-N̲1–N10–C̲C(H)(R)}] (N1–N10 = Me2phen) containing a Pt–N–C–C–N–C six membered metallacycle.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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