An unexpected all-metal aromatic tetranuclear silver cluster in human copper chaperone Atox1

Author:

Wang Xiuxiu12,Han Zong-Chang3,Wei Wei124ORCID,Hu Hanshi3ORCID,Li Pengfei5,Sun Peiqing1,Liu Xiangzhi2,Lv Zhijia6,Wang Feng6,Cao Yi5,Guo Zijian17ORCID,Li Jun38ORCID,Zhao Jing1274ORCID

Affiliation:

1. State Key Laboratory of Coordination Chemistry, Chemistry and Biomedicine Innovation Center (ChemBIC), School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

2. School of Life Sciences, Nanjing University, Nanjing 210023, China

3. Department of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Tsinghua University, Beijing 100084, China

4. Shenzhen Research Institute, Nanjing University, Shenzhen 518000, China

5. National Laboratory of Solid State Microstructure, Department of Physics, Nanjing University, Nanjing 210023, China

6. Elias James Corey Institute of Biomedical Research, Wuxi Biortus Biosciences Co., Ltd, Jiangyin 214437, China

7. Nanchuang (Jiangsu) Institute of Chemistry and Health, Nanjing 210023, China

8. Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, China

Abstract

Metal clusters, such as iron–sulfur clusters, play key roles in sustaining life and are intimately involved in the functions of metalloproteins.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Guangdong Provincial Key Laboratory of Catalysis

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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