Fluorescent phenanthridine-based calix[4]arene derivatives: synthesis and thermodynamic and computational studies of their complexation with alkali-metal cations

Author:

Bakić Marina Tranfić12345,Jadreško Dijana645,Hrenar Tomica78345,Horvat Gordan78345,Požar Josip78345,Galić Nives78345,Sokol Vesna91011125,Tomaš Renato91011125,Alihodžić Sulejman1345,Žinić Mladen1415165,Frkanec Leo645,Tomišić Vladislav78345

Affiliation:

1. Department of Chemistry and Biochemistry

2. Faculty of Food Technology and Biotechnology

3. University of Zagreb

4. 10000 Zagreb

5. Croatia

6. Ruđer Bošković Institute

7. Department of Chemistry

8. Faculty of Science

9. Division of Chemistry

10. Faculty of Chemistry and Technology

11. University of Split

12. 21000 Split

13. Fidelta Ltd.

14. Croatian Academy of Sciences and Arts

15. Zagreb and Baltazar University of Applied Sciences

16. 10290 Zaprešić

Abstract

The novel calix[4]arenes exhibiting prominent fluorescence were shown to be potential sensitive fluorimetric cation sensors. Comprehensive experimental and computational studies provided detailed insight into the corresponding complexation reactions.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference64 articles.

1. Calixarenes, Macrocycles with(Almost) Unlimited Possibilities

2. Coordination chemistry of calix[4]arene derivatives with lower rim functionalisation and their applications

3. D. C. Gutsche , in Calixarenes: An Introduction (Monographs in Supramolecular Chemistry), ed. J. F. Stoddard, RSC Publishing, Cambridge, 2nd edn, 2008

4. Lower-Rim Substituted Calixarenes and Their Applications

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