Iridium-mediated C–S bond activation and transformation: organoiridium(iii) thioether, thiolato, sulfinato and thiyl radical compounds. Synthesis, mechanistic, spectral, electrochemical and theoretical aspects-Reference-Cited by-同舟云学术

Iridium-mediated C–S bond activation and transformation: organoiridium(iii) thioether, thiolato, sulfinato and thiyl radical compounds. Synthesis, mechanistic, spectral, electrochemical and theoretical aspects

Published:2015 Issue:18 Volume:44 Page:8625-8639
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Das Ujjwal¹²³⁴⁵,Ghorui Tapas¹²³⁴⁵,Adhikari Basab¹²³⁴⁵,Roy Sima¹²³⁴⁵,Pramanik Shuvam¹²³⁴⁵,Pramanik Kausikisankar¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Inorganic Chemistry Section

3. Jadavpur University

4. Kolkata – 700032

5. India

Abstract

The iridium-mediated C–S bond scission by an uncommon SET reductive process: exploration of S-centered reactivity of iridium(iii) thiolato complex.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00448A

Reference105 articles.

1. Transition-metal mediated carbon–sulfur bond activation and transformations

2. Transition metal-catalyzed C–C bond formation via C–S bond cleavage: an overview

3. Bis(bipyridine)ruthenium(II) Complexes with an Aliphatic Sulfinato Donor: Synthesis, Characterization, and Properties

4. Description of the Ground-State Covalencies of the Bis(dithiolato) Transition-Metal Complexes from X-ray Absorption Spectroscopy and Time-Dependent Density-Functional Calculations

5. First-Principles Simulations of C−S Bond Cleavage in Rhenium Thioether Complexes

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