Computational insights into different regioselectivities in the Ir-porphyrin-catalyzed C–H insertion reaction of quinoid carbene-Reference-Cited by-同舟云学术

Computational insights into different regioselectivities in the Ir-porphyrin-catalyzed C–H insertion reaction of quinoid carbene

Published:2022 Issue:4 Volume:9 Page:1143-1151
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Chen Xiahe¹,Cao Chaoqin¹,Yang Yun-Fang¹^ORCID,She Yuan-Bin¹^ORCID

Affiliation:

1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China

Abstract

Carbene insertion into the secondary C–H bond of 1-methyl-1,3-cyclohexadiene and the primary C–H bond of 1-methylcyclohexene follows the HAA-O and HAA-C pathway, respectively.

Funder

National Natural Science Foundation of China

Zhejiang University of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D1QO01727F

Reference51 articles.

1. Selective functionalisation of saturated C–H bonds with metalloporphyrin catalysts

2. Catalytic C–H functionalization by metalloporphyrins: recent developments and future directions

3. Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins

4. Computational Exploration of Chiral Iron Porphyrin-Catalyzed Asymmetric Hydroxylation of Ethylbenzene Where Stereoselectivity Arises from π–π Stacking Interaction

5. Mechanism and stereoselectivity of benzylic C–H hydroxylation by Ru–porphyrin: a computational study

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