A breathing MOF: direct crystallographic observation of the site-selective C(sp3)–H functionalization-Reference-Cited by-同舟云学术

A breathing MOF: direct crystallographic observation of the site-selective C(sp3)–H functionalization

Published:2016 Issue:57 Volume:6 Page:51936-51940
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Shi Dongying¹²³⁴,Zeng Le¹²³⁴,Ming Zheng¹²³⁴,He Cheng¹²³⁴,Meng Changgong¹²³⁴,Duan Chunying¹²³⁴

Affiliation:

1. State Key Laboratory of Fine Chemicals

2. Dalian University of Technology

3. Dalian 116024

4. P. R. China

Abstract

A 3D breathing MOF was synthesized for light-driven acceleration of the site-selective C(sp³)–H activation. The 1D channels of the assembled MOF can encapsulate reaction substrates via a breathing process that were observed by single-crystal X-ray analyses.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA07100G

Reference39 articles.

1. Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds

2. Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations

3. Functionalization of C(sp 3 )–H bonds using a transient directing group