[3]Foldarotaxane-mediated synthesis of an improbable [2]rotaxane

Author:

Koehler Victor1,Gauthier Maxime2,Yao Chenhao1,Fournel-Marotte Karine2,Waelès Philip2,Kauffmann Brice3ORCID,Huc Ivan4ORCID,Coutrot Frédéric2ORCID,Ferrand Yann1

Affiliation:

1. Institut de Chimie et Biologie des Membranes et Nano-objets CBMN (UMR5248), Université de Bordeaux, CNRS, IPB, 2 rue Robert Escarpit, 33600, Pessac, France

2. Supramolecular Machines and Archtectures Team, IBMM, Univ Montpellier, CNRS, ENSCM, Montpellier, France

3. Université de Bordeaux, CNRS, INSERM, UMS3033, IECB, 2 rue Robert Escarpit, 33600, Pessac, France

4. Department of Pharmacy, Ludwig-Maximilians-Universität, Butenandtstr. 5–13, 81377, München, Germany

Abstract

The wrapping of a helix around the axle of a [2]rotaxane induced compartmentalization by sequestrating the macrocycle around a part of the axle for which it has no affinity. It gave this way the opportunity to yield an improbable [2]rotaxane.

Funder

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Université de Bordeaux

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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