Single-component panchromatic white light generation, and tuneable excimer-like visible orange and NIR emission in a Dy quinolinolate complex

Author:

Mara Dimitrije1ORCID,Pilia Luca2ORCID,Van de Steen Maxim3,Miletto Ivana4ORCID,Zeng Min5,Van Hecke Kristof3ORCID,Serpe Angela6ORCID,Deplano Paola6ORCID,Van Deun Rik3ORCID,Artizzu Flavia34ORCID

Affiliation:

1. Department of Chemistry, KU Leuven, Celestijnenlaan 200D, 3001, Leuven, Belgium

2. Department of Chemical, Mechanical and Materials Engineering, Cagliari State University, via Marengo 2, 09123, Cagliari, Italy

3. Department of Chemistry, Ghent University, Krijgslaan 281-S3, 9000, Ghent, Belgium

4. Department of Sciences and Technological Innovation, University of Eastern Piedmont “Amedeo Avogadro”, Viale Teresa Michel, 11, 15121 Alessandria, Italy

5. Hubei Key Laboratory of Ferro & Piezoelectric Materials and Devices, Faculty of Physics & Electronic Sciences, Hubei University, Wuhan 430062, China

6. Department of Civil, Environmental and Architectural Engineering, Cagliari State University, via Marengo 2, 09123, Cagliari, Italy

Abstract

Extensive π-stacking interactions in a crystalline mononuclear Dy complex give rise to phase-sensitive color-tuneable emission and pure white light generation and allow for intense Dy NIR emission by photoexcitation over a broad spectral range.

Funder

Fonds Wetenschappelijk Onderzoek

KU Leuven

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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