Selective preparative ‘oxidase phase’ in sesquiterpenoids: the radical approach-Reference-Cited by-同舟云学术

Selective preparative ‘oxidase phase’ in sesquiterpenoids: the radical approach

Published:2023 Issue:8 Volume:10 Page:2095-2114
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Kourgiantaki Maria¹,Bagkavou Georgia G.¹,Stathakis Christos I.¹^ORCID,Zografos Alexandros L.¹^ORCID

Affiliation:

1. Aristotle University of Thessaloniki, Department of Chemistry, University Campus, Thessaloniki 54124, Greece

Abstract

Juggling between reactivity and selectivity, free radical oxidation offers a unique means to synthesize natural products in a direct and efficient way. The case study of sesquiterpenes is illustrative of how modern total synthesis should be conducted.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00314K

Reference112 articles.

1. “Common synthetic scaffolds” in the synthesis of structurally diverse natural products

2. Combining the best of both worlds: radical-based divergent total synthesis

3. Advances in Catalytic Aerobic Oxidations by Activation of Dioxygen-Monooxygenase Enzymes and Biomimetics

4. Enantioselective Epoxidation of Unfunctionalized Olefins with Molecular Oxygen and Aldehyde Catalyzed by Optically Active Manganese(III) Complexes

5. β-Selective Epoxidation of Cholesterol Derivatives with Molecular Oxygen and Aldehyde Catalyzed by Manganese(II) Complex

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Iron(ΙΙΙ) Catalyzed Aerobic C_α−C_β Cleavage of Allylic Alcohols;European Journal of Organic Chemistry;2024-08-02

2. Climbing the Oxidase Phase Ladder by Using Dioxygen as the Sole Oxidant: The Case Study of Costunolide;Organic Letters;2024-03-29

3. Routes to Advanced Intermediates in the Synthesis of Tetracarbocyclic Sesquiterpenoids Daphnenoid A and Artatrovirenols A and B;Organic Letters;2024-02-19

4. Advancements in the synthesis of polyoxygenated oxepanes and thiepanes for applications to natural products;Organic Chemistry Frontiers;2024

5. Strategic convergent synthesis en route to Veratrum steroidal alkaloids;Organic Chemistry Frontiers;2024