Voltammetric optimisation of TEMPO-mediated oxidations at cellulose fabric
Author:
Affiliation:
1. Department of Chemistry
2. University of Bath
3. Bath, UK
4. Centre for Sustainable Chemical Technologies
Abstract
A simple method for rapid voltammetric screening of N-oxyl based mediators and reaction conditions for electrochemical oxidation of cellulose is described. Using immobilised cellulose (cotton cloth) the screening requires small quantities of mediator and yet yields information about relative efficiency of mediator, optimum pH, and preferred buffer identity.
Publisher
Royal Society of Chemistry (RSC)
Subject
Pollution,Environmental Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/GC/C4GC00306C
Reference26 articles.
1. Formation of shear thinning gels from partially oxidised cellulose nanofibrils
2. Ion-exchange behavior of carboxylate groups in fibrous cellulose oxidized by the TEMPO-mediated system
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4. Homogeneous Suspensions of Individualized Microfibrils from TEMPO-Catalyzed Oxidation of Native Cellulose
5. A new bio-based nanocomposite: fibrillated TEMPO-oxidized celluloses in hydroxypropylcellulose matrix
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