Magnesium bromide (MgBr2) as a catalyst for living cationic polymerization and ring-expansion cationic polymerization-Reference-Cited by-同舟云学术

Magnesium bromide (MgBr2) as a catalyst for living cationic polymerization and ring-expansion cationic polymerization

Published:2021 Issue:5 Volume:12 Page:702-710
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Daito Yuji¹²³⁴⁵,Kojima Reina¹²³⁴⁵,Kusuyama Naoyuki¹²³⁴⁵,Kohsaka Yasuhiro⁶⁷⁵⁸⁷^ORCID,Ouchi Makoto¹²³⁴⁵^ORCID

Affiliation:

1. Department of Polymer Chemistry

2. Graduate School of Engineering

3. Kyoto University

4. Kyoto 615-8510

5. Japan

6. Research Initiative for Supra-Materials (RISM)

7. Shinshu University

8. Faculty of Textile Science and Technology

Abstract

Magnesium bromide (MgBr₂) was found to be an effective catalyst for the ring-expansion cationic polymerizations of isobutyl vinyl ether (IBVE) initiated by a “cyclic” hemiacetal ester (HAE) bond-based initiator leading to the syntheses of cyclic poly(IBVE)s.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2021/PY/D0PY01584A

Reference44 articles.

1. Modern cationic vinyl polymerization

2. A Renaissance in Living Cationic Polymerization

3. Stereoregulation in Cationic Polymerization by Designed Lewis Acids. 1. Highly Isotactic Poly(isobutyl vinyl ether) with Titanium-Based Lewis Acids