Formal allylic C(sp<sup>3</sup>)–H alkylation of α-alkylstyrenes by rearrangement of intermediate alkenyl sulfonium salts-Reference-Cited by-同舟云学术

Formal allylic C(sp³)–H alkylation of α-alkylstyrenes by rearrangement of intermediate alkenyl sulfonium salts

Published:2023 Issue:13 Volume:10 Page:3275-3279
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Shao Zeyu¹,Zhou Junqi¹,Wang Ziyu¹,Liu Biao¹,Zou Liang-Hua¹^ORCID,Wang Cheng¹,Wen Jian¹^ORCID

Affiliation:

1. School of Life Sciences and Health Engineering, Jiangnan University, Wuxi, Jiangsu, 214122, People's Republic of China

Abstract

Allylic C(sp3)–H alkylation of α-alkylstyryl sulfonium salts based on [2,3]-sigmatropic rearrangement strategies has been developed. This protocol could allow facile access to allylated carbon quaternary centers in moderate to good yields.

Funder

Natural Science Foundation of Jiangsu Province

Fundamental Research Funds for the Central Universities

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00459G

Reference44 articles.

1. Transition Metal–Catalyzed Allylic C(sp 3 )–H Functionalization via η 3 ‐Allylmetal Intermediate

2. Recent advances in oxidative allylic C–H functionalization via group IX-metal catalysis

3. Asymmetric Transition-Metal-Catalyzed Allylic Alkylations: Applications in Total Synthesis

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