Rhodium(iii)-catalyzed dehydrogenative dialkenylation of the monocarba-closo-decaborate cluster by regioselective B

Rhodium(iii)-catalyzed dehydrogenative dialkenylation of the monocarba-closo-decaborate cluster by regioselective B–H activation

Published:2018 Issue:88 Volume:54 Page:12451-12454
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Liang Xuewei¹²³⁴,Shen Yunjun¹²³⁴,Zhang Kang¹²³⁴,Liu Jiyong¹²³⁴,Duttwyler Simon¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Zhejiang University

3. 310027 Hangzhou

4. P. R. China

Abstract

The regioselective double B–H activation of the {CB₉} carborane by rhodium catalysis is reported, affording novel inorganic–organic hybrid clusters.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC05983G

Reference70 articles.

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4. Monocarbaborane Anions with 10 or 12 Vertices

5. Update 1 of:Chemistry of the Carba-closo-dodecaborate(−) Anion, CB11H12–

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