Circularly polarized blue fluorescence based on chiral heteroleptic six-coordinate bis-pyrazolonate-Zn2+ complexes

Author:

Liu Jiaxiang1,Zhao Yuzhen1,Zhang Zhe1,Li Manni1,Song Wenqi1,Li Wentao2ORCID,Miao Zongcheng3ORCID

Affiliation:

1. Xi'an Key Laboratory of Advanced Photo-Electronics Materials and Energy Conversion Device, Technological Institute of Materials & Energy Science (TIMES), Xijing University, Xi'an 710123, P. R. China

2. College of Big Data and Information Engineering, Institute of Advanced Optoelectronic Materials and Technology, Guizhou University, Guiyang 550025, P. R. China

3. School of Artificial Intelligence, Optics and Electronics (iOPEN), Northwestern Polytechnical University, Xi'an 710072, P. R. China

Abstract

Based on a conceptual approach to a new pair of chiral heteroleptic bis-pyrazolonate-Zn2+ enantiomers R,R-Zn2+ and S,S-Zn2+, they not only show perfect chiral character of the ground- and excited-state, but also exhibit high-quality pure blue fluorescence.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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