Insight into the preferential N-binding versus O-binding of nitrosoarenes to ferrous and ferric heme centers
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. University of Oklahoma
3. Norman
4. USA
5. Department of Chemistry and Chemical Biology
6. Stevens Institute of Technology
7. Castle Point on Hudson
8. Hoboken
Abstract
The dominant stabilization forces in the observed ferrous N-coordination, and ferric O-coordination, of nitrosoarenes to hemes are provided by dπ–pπ* and dσ–pπ* interactions, respectively.
Funder
National Institute of General Medical Sciences
Division of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03604H
Reference89 articles.
1. Erythrocyte enzymes catalyze 1-nitropyrene and 3-nitrofluoranthene nitroreduction
2. Reduction of polynitroaromatic compounds: the bacterial nitroreductases
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