Characterisation of Pb2Rh2O7 and Y2Rh2O7: an unusual case of pyrochlore stabilisation under high pressure, high temperature synthesis conditions-Reference-Cited by-同舟云学术

Characterisation of Pb₂Rh₂O₇ and Y₂Rh₂O₇: an unusual case of pyrochlore stabilisation under high pressure, high temperature synthesis conditions

Published:2024 Issue:9 Volume:12 Page:3077-3089
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Injac Sean D.¹²^ORCID,Mullens Bryce G.³^ORCID,Denis Romero Fabio¹^ORCID,Avdeev Maxim³⁴^ORCID,Barnett Christopher³^ORCID,Yuen Alexander K. L.³^ORCID,Amano Patino Midori¹^ORCID,Mukherjee Supratik⁵^ORCID,Vaitheeswaran Ganapathy⁶^ORCID,Singh David J.⁷,Kennedy Brendan J.³^ORCID,Shimakawa Yuichi¹^ORCID

Affiliation:

1. Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto, 611-0011, Japan

2. Centre for Science at Extreme Conditions and School of Chemistry, University of Edinburgh, Peter Guthrie Tait Road, Edinburgh, EH9 3FD, UK

3. School of Chemistry, University of Sydney, Sydney, New South Wales 2006, Australia

4. Australian Nuclear Science and Technology Organisation, Lucas Heights, New South Wales 2234, Australia

5. Advanced Center of Research in High Energy Materials, University of Hyderabad, Prof. C.R. Rao Road, Gachibowli, Hyderabad 500046, Telangana, India

6. School of Physics, University of Hyderabad, Prof. C.R. Rao Road, Gachibowli, Hyderabad 500046, Telangana, India

7. Department of Physics and Astronomy, University of Missouri-Columbia, Columbia, MO65211, USA

Abstract

We synthesised new Rh oxides using high pressure, high temperature techniques. The counter-intuitive stabilisation of a lower density structure at high pressures furthers the utility of the synthesis technique and introduces a new class of Rh oxides.

Funder

University of Hyderabad

Ministry of Education, Culture, Sports, Science and Technology

Advanced Centre of Research in High Energy Materials, University of Hyderabad

Japan Science and Technology Agency

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TC/D3TC04389D

Reference82 articles.

1. Oxide pyrochlores — A review

2. High-Performance Pyrochlore-Type Yttrium Ruthenate Electrocatalyst for Oxygen Evolution Reaction in Acidic Media

3. Potential of pyrochlore structure materials in solid oxide fuel cell applications

4. Single crystal CsTaWO 6 nanoparticles for photocatalytic hydrogen production

5. Magnetic frustration in lead pyrochlores