Reaction mechanism of the selective reduction of CO2 to CO by a tetraaza [CoIIN4H]2+ complex in the presence of protons-Reference-Cited by-同舟云学术

Reaction mechanism of the selective reduction of CO2 to CO by a tetraaza [CoIIN4H]2+ complex in the presence of protons

Published:2018 Issue:37 Volume:20 Page:24058-24064
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Garza Alejandro J.¹²³,Pakhira Srimanta⁴⁵³⁶⁵^ORCID,Bell Alexis T.¹²³⁷²^ORCID,Mendoza-Cortes Jose L.¹²³⁴⁵^ORCID,Head-Gordon Martin¹²³⁸²^ORCID

Affiliation:

1. Joint Center for Artificial Photosynthesis, Lawrence Berkeley National Laboratory

2. Berkeley

3. USA

4. Department of Physics, Scientific Computing, Materials Science and Engineering, High Performance Material Institute, Condensed Matter Theory-National High Magnetic Field Laboratory, Florida State University

5. Tallahassee

6. Department of Chemical & Biomedical Engineering, Florida A&M University – Florida State University, Joint College of Engineering

7. Department of Chemical and Biomolecular Engineering, University of California

8. Department of Chemistry, University of California

Abstract

The tetraaza [Co^IIN₄H]²⁺ complex (1) is remarkable for its ability to selectively reduce CO₂ to CO with 45% Faradaic efficiency and a CO to H₂ ratio of 3 : 2.

Funder

U.S. Department of Energy

Florida State University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CP/C8CP01963K

Reference55 articles.

1. Hydrogen Evolution Catalyzed by Cobaloximes

2. Electrocatalytic Hydrogen Evolution at Low Overpotentials by Cobalt Macrocyclic Glyoxime and Tetraimine Complexes