Reduction of hypervalent iodine by coordination to iron(iii) and the crystal structures of PhIO and PhIO2-Reference-Cited by-同舟云学术

Reduction of hypervalent iodine by coordination to iron(iii) and the crystal structures of PhIO and PhIO2

Published:2016 Issue:44 Volume:45 Page:17714-17722
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wegeberg Christina¹²³⁴⁵,Frankær Christian Grundahl⁶⁷⁸⁵,McKenzie Christine J.¹²³⁴⁵

Affiliation:

1. Department of Physics

2. Chemistry and Pharmacy

3. University of Southern Denmark

4. 5230 Odense M

5. Denmark

6. Department of Chemistry

7. Technical University of Denmark

8. Kongens Lyngby

Abstract

Iodine L₃-edge XANES spectra using reference compounds with formal iodine oxidation states spanning −1 to +7 show that iodine in an Fe(iii) coordinated iodosylbenzene (PhIO) is reduced compared to parent hypervalent PhIO which has been structurally characterized.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02937J

Reference31 articles.

1. Halogen-Bonding-Assisted Iodosylbenzene Activation by a Homogenous Iron Catalyst

2. An Iron(III) Iodosylbenzene Complex: A Masked Non-Heme FeVO

3. The Cambridge Structural Database: a quarter of a million crystal structures and rising

4. Zur Kenntniss aromatischer Jodidchloride, des Jodoso‐ und Jodobenzols

5. An examination of the structures of iodosylbenzene (PhIO) and the related imido compound, PhINSO2-4-Me-C6H4, by X-ray powder diffraction and EXAFS (extended X-ray absorption fine structure) spectroscopy

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